Second Generation
Second generation materials have been developed to address energy requirements and production costs of solar cells. Alternative manufacturing techniques such as vapour deposition, electroplating, and use of Ultrasonic Nozzles are advantageous as they reduce high temperature processing significantly. It is commonly accepted that as manufacturing techniques evolve production costs will be dominated by constituent material requirements. But the defects inherent in the lower quality processing methods, have much reduced efficiencies compared to First Generation. The most successful second generation materials have been cadmium telluride, copper indium gallium selenide, amorphous silicon and micromorphous silicon. These materials are applied in a thin film to a supporting substrate such as glass or ceramics reducing material mass and therefore costs.
- thin film cell technology (Thin-Film Photovoltaic Cell)
In the begginig of the 1990s there has been increased development of thin-film processes for manufacturing solar cells. In these, photoactive semiconductors are applied as thin layers to a low-cost substrate (in most cases, glass). The methods used include vapour deposition, sputter processes (cathode sputtering) and electrolytic baths with a lot of layers. The thickness range of such a layer is wide and varies from a few nanometers to tens of micrometers. Many different photovoltaic materials are deposited with various deposition methods on a variety of substrates. Thin Film Solar Cells are usually categorized according to the photovoltaic material used. Thin-film cells are not restricted in their format to standard wafer sizes, as is the case with crystalline cells. Theoretically, the substrate can be cut to any size and coated with semiconductor material. However, because only cells of the same size can be connected in series for internal wiring, for practical purposes only rectangular formats are common. Despite the relatively low efficiency, the energy yield can, under certain conditions, be quite considerable. The utilization of diffuse and low light is better with thin-film cells and there is a more favourable temperature coefficient (i.e. the decrease in performance at higher operating temperatures is less than with other technologies). Thin-film cells are less sensitive to shading!!!